• 文献标题:   Using glucosamine as a reductant to prepare reduced graphene oxide and its nanocomposites with metal nanoparticles
  • 文献类型:   Article
  • 作  者:   LI CB, WANG XR, LIU Y, WANG W, WYNN J, GAO JP
  • 作者关键词:   graphene oxide, glucosamine, metal nanoparticle, catalysi, surfaceenhanced raman scattering
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   20
  • DOI:   10.1007/s11051-012-0875-8
  • 出版年:   2012

▎ 摘  要

A green and facile approach of producing reduced graphene oxide (RGO) by the reduction of graphene oxide (GO) with a monosaccharide medicine glucosamine (GL) was developed. The effect of several factors on the GO reduction, including pH, the weight ratio of GL/GO, and the reaction temperature was studied. The deoxygenation process was monitored with UV-Vis absorption spectroscopy, and the reducing degree of GO was determined with X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, thermo-gravimetric analysis, X-ray photoelectron spectroscopy, and transmission electron microscopy. Au nanoparticles (about 3.3-4.2 nm) (AuNPs)/RGO and Ag nanoparticles (about 6 nm) (AgNPs)/RGO materials were prepared in two different ways using the above reduction method. They were then used to catalyze the Suzuki-Miyaura coupling reaction of phenyl halide and phenylboronic acid to produce biphenyl, and the highest yield of biphenyl for AuNPs/RGO was 99 %. In addition, the AgNPs/RGO materials exhibited a surface-enhanced Raman scattering effect, and some RGO peaks were enhanced. This approach opens up a new, practical, and green reducing method to prepare RGO for large-scale practical application.