• 文献标题:   Graphene-doped carbon xerogel combining high electrical conductivity and surface area for optimized aqueous supercapacitors
  • 文献类型:   Article
  • 作  者:   CANALRODRIGUEZ M, ARENILLAS A, REYRAAP N, RAMOSFERNANDEZ G, MARTINGULLON I, MENENDEZ JA
  • 作者关键词:   carbon xerogel, graphene oxide, graphene, supercapacitor
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   CSIC
  • 被引频次:   22
  • DOI:   10.1016/j.carbon.2017.03.059
  • 出版年:   2017

▎ 摘  要

A graphene doped carbon xerogel was synthesized by simply replacing the water (solvent) by an aqueous well-dispersed graphene oxide stable suspension in the precursor mixture used for the synthesis of the organic xerogel. During the carbonization of the organic xerogel, the graphene oxide sheets are reduced to graphene, which is embedded and well dispersed within the carbon xerogel matrix. Only a small minimum amount of graphene oxide is necessary to interconnect the graphene sheets throughout the carbon xerogel. This material has both a high porosity and an excellent electrical conductivity so that, when used as electrode in aqueous supercapacitors at high current density, it provides them with 25% more capacitance and 100% more power than the undoped carbon xerogels. The synthesis conditions, characteristics of the carbons and how these affect the electrical conductivity and performance of the materials in the supercapacitors are discussed. (C) 2017 Elsevier Ltd. All rights reserved.