• 文献标题:   Enhanced photocatalytic property of BiFeO3/N-doped graphene composites and mechanism insight
  • 文献类型:   Article
  • 作  者:   LI P, LI L, XU MJ, CHEN Q, HE YB
  • 作者关键词:   bifeo3, ndoped graphene, band bending, photocatalytic activity
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Hubei Univ
  • 被引频次:   18
  • DOI:   10.1016/j.apsusc.2016.11.052
  • 出版年:   2017

▎ 摘  要

A series of BiFeO3/(N-doped) graphene composites are prepared by a facile hydrothermal method. BiFeO3/N-doped graphene shows photocatalytic performance superior to that of BiFeO3/graphene and pristine BiFeO3. The enhanced photo-degradation performance of BiFeO3/N-doped graphene are mainly attributable to the improved light absorbance of the composite, abundant active adsorption sites and high electrical charge mobility of N-doped graphene, and the downward band bending of BiFeO3 at the composite interface. In particular, X-ray photoelectron spectroscopy analyses reveal that the electron energy band of BiFeO3 is downward bent by 1.0 eV at the interface of BiFeO3/N-doped graphene, because of different work functions of both materials. This downward band bending facilitates the transfer of photogenerated electrons from BiFeO3 to N-doped graphene and prompts the separation of photo-generated electron-hole pairs, leading eventually to the enhanced photocatalytic performance. (C) 2016 Elsevier B.V. All rights reserved.