• 文献标题:   Copper-Coated Graphene Nanoplatelets-Reinforced Al-Si Alloy Matrix Composites Fabricated by Stir Casting Method
  • 文献类型:   Article, Early Access
  • 作  者:   HAN XQ, YANG LZ, ZHAO NQ, HE CN
  • 作者关键词:   alsi alloy, graphene, stir casting, wettability, si phase refinement
  • 出版物名称:   ACTA METALLURGICA SINICAENGLISH LETTERS
  • ISSN:   1006-7191 EI 2194-1289
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   0
  • DOI:   10.1007/s40195-020-01112-1 EA AUG 2020
  • 出版年:  

▎ 摘  要

In this study, Cu nanoparticles-coated graphene nanoplatelets (Cu-NPs@GNPs) were synthesized by a simple in situ method with the assistance of NaCl templates and used for reinforcing Al-10Si composites through stir casting process. The experimental results showed that the coating of Cu-NPs on the GNPs could compromise the density mismatch between GNPs and metal matrix and effectively hinder the float of GNPs during stirring. The reaction of Cu-NPs and Al matrix could protect the structural integrity of GNPs as well as improve the interfacial wettability between GNPs and the matrix, thus promoting the uniform dispersion of GNPs in the composites. As a result, the as-prepared 0.5 wt% Cu-NPs@GNPs/Al-10Si composite exhibited a tensile strength of 251 MPa (45% higher than the Al-10Si) with a total elongation of 15%. The strengthening effects were mainly attributed to the following three reasons: Firstly, the Cu-NPs coating improved the interfacial bonding between GNPs and Al matrix which promoted the load transfer from the matrix to the GNPs. Secondly, the nanoscale Al2Cu formed by the reaction of Cu-NPs and Al matrix played a role in precipitation strengthening. Thirdly, GNPs refined the silicon phases and improved the monolithic performances of the composites.