• 文献标题:   Graphene-Enhanced Raman Scattering from the Adenine Molecules
  • 文献类型:   Article
  • 作  者:   DOLGOV L, PIDHIRNYI D, DOVBESHKO G, LEBEDIEVA T, KIISK V, HEINSALU S, LANGE S, JAANISO R, SILDOS I
  • 作者关键词:   graphene, raman scattering, chemical enhancement, adenine
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1556-276X
  • 通讯作者地址:   NAS Ukraine
  • 被引频次:   3
  • DOI:   10.1186/s11671-016-1418-5
  • 出版年:   2016

▎ 摘  要

An enhanced Raman scattering from a thin layer of adenine molecules deposited on graphene substrate was detected. The value of enhancement depends on the photon energy of the exciting light. The benzene ring in the structure of adenine molecule suggests p-stacking of adenine molecule on top of graphene. So, it is proposed that the enhancement in the adenine Raman signal is explained by the resonance electron transfer from the Fermi level of graphene to the lowest unoccupied molecular orbital (LUMO) level of adenine.