▎ 摘　　要

We report a method to prepare the poly(vinyl alcohol)/reduced graphene oxide (PVA/rGO) nanocomposites with low percolation threshold and high electrical conductivity by using the large-area reduced graphene oxide (LrGO) sheets. The large-area graphene oxide (LGO) sheets are expected to overlap better with each other and form the continuous GO network in PVA matrix than small-area graphene oxide (SGO). During the thermal reduction process, the LGO sheets are easily restored and improve the electrical conductivity of nanocomposites due to their low damage level of conjugate-structure. As a result, the percolation threshold of PVA/LrGO nanocomposites is similar to 0.189 wt% lower than present reports (0.5 similar to 0.7 wt%). At the LrGO content of 0.7 wt%, the electrical conductivity of PVA/LrGO nanocomposites reaches 6.3.10(-3) S/m. Besides that, this method only takes 15 similar to 30 min to reduce the PVA/GO nanocomposites effectively.