• 文献标题:   High quality graphene-semiconducting oxide heterostructure for inverted organic photovoltaics
  • 文献类型:   Article
  • 作  者:   SHIN KS, JO H, SHIN HJ, CHOI WM, CHOI JY, KIM SW
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Sungkyunkwan Univ SKKU
  • 被引频次:   29
  • DOI:   10.1039/c2jm00072e
  • 出版年:   2012

▎ 摘  要

In this work, we demonstrate damage-free direct growth of high-quality semiconducting ZnO thin films on thermal chemical vapor deposition (CVD)-grown graphene transferred onto a plastic substrate. A mist pyrolysis CVD (MPCVD) method based on a non-vacuum process at a low growth temperature of 160 degrees C is introduced for the successful direct growth of ZnO on graphene without any additional treatments or processes. ZnO thin films that did not exhibit damage to the structural and electrical properties of graphene were successfully grown on graphene. The MPCVD-grown ZnO thin films revealed more uniform surface morphology and better structural property than ZnO thin films deposited using sol-gel and sputtering. Using the ZnO/graphene heterostructure, we fabricated bulk heterojunction inverted organic photovoltaics with a power conversion efficiency of 1.55%.