• 文献标题:   Hierarchically nanostructured ZnCo2O4 particles in 3D graphene networks for high-rate and long-life lithium ion batteries
  • 文献类型:   Article
  • 作  者:   YANG Y, LI ZH, XU SS, TANG YB, LEE CS, ZHANG WJ
  • 作者关键词:   znco2o4, hierarchical, 3d graphene, anode lithium ion battery
  • 出版物名称:   MATERIALS TODAY ENERGY
  • ISSN:   2468-6069
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   5
  • DOI:   10.1016/j.mtener.2018.11.002
  • 出版年:   2019

▎ 摘  要

Hierarchical ZnCo2O4 particles hosted by 3D graphene network were synthesized through a one-pot hydrothermal synthesis approach. The as-synthesized ZnCo2O4-graphene composites showed an outstanding overall electrochemical performance as an anode of lithium ion batteries with high specific capacity and excellent cycling stability, i.e., a reversible capacity of 1920 mAh g(-1 )at a current density of 1000 mA g(-1) after 300 cycles. In particular, at an elevated current density of 4000 mA g(-1), a high capacity of 1100 mAh g(-1) could still be achieved, and it dropped by only 34% to 730 mAh g(-1) after 2000 cycles. The synergistic roles of the hierarchically nanostructured ZnCo2O4 and highly-conductive 3D graphene networks in improving the specific capacity, rate performance, and cycling stability were discussed. (C) 2018 Elsevier Ltd. All rights reserved.