• 文献标题:   The role of physical structure and morphology on the photodegradation behaviour of polypropylene-graphene oxide nanocomposites
  • 文献类型:   Article
  • 作  者:   DE OLIVEIRA YDC, AMURIN LG, VALIM FCF, FECHINE GJM, ANDRADE RJE
  • 作者关键词:   graphene oxide, polypropylene, nanocomposite
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:   Univ Prebiteriana Mackenzie
  • 被引频次:   7
  • DOI:   10.1016/j.polymer.2019.05.029
  • 出版年:   2019

▎ 摘  要

In this work, for the first time, the effect of graphene oxide on the photodegradation behaviour of polypropylene-graphene oxide nanocomposites is presented. The graphene oxide was characterised, and AFM images show that the GO can be classified as multilayer-GO (mGO). Based on previous work, two new methods were used, liquid-phase feeding (LPF) and solid-solid deposition (SSD), to insert pre-exfoliated mGO into the polymer matrix. Moreover, the morphology and structure of the nanocomposites were analysed using an optical microscope, rheological and dynamic mechanical analysis, x-ray diffraction, and differential scanning calorimetry. The results show that stacked layers are obtained, especially for the SSD method, since it decreases the nanocomposites viscosity, mostly due to the self-lubricity of mGO layers. Finally, the photodegradation behaviour was investigated and revealed that mGO plays an important role, with a factor of three increase regarding photodegradation resistance, when compared to pure polypropylene.