• 文献标题:   Bendable RuO2/graphene thin film for fully flexible supercapacitor electrodes with superior stability
  • 文献类型:   Article
  • 作  者:   CHO S, KIM J, JO Y, AHMED ATA, CHAVAN HS, WOO H, INAMDAR AI, GUNJAKAR JL, PAWAR SM, PARK Y, KIM H, IM H
  • 作者关键词:   ruthenium oxide, graphene, supercapacitor, flexible substrate
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Dongguk Univ
  • 被引频次:   14
  • DOI:   10.1016/j.jallcom.2017.07.135
  • 出版年:   2017

▎ 摘  要

Ruthenium oxide (RuO2) is fabricated on graphene (Gr)-coated Copper (Cu) foil by using a cathodic electroplating technique for flexible supercapacitor electrode applications. The electrochemical properties of the RuO2/Gr/Cu electrode are investigated with a conventional three electrode configuration in 0.5 M H2SO4 electrolyte. The graphene insertion layer plays a key role in improving the structural and electrochemical properties of the RuO2 electrode film under the bent condition. The electrode exhibits a specific capacitance of 1561 F g(-1) (0.015 F cm(-1)) at a scan rate of 5 mV s(-1) and a significantly improved retention of 98% under the bent condition. The flexible RuO2/Gr/Cu electrode exhibits a high energy density of similar to 13 Wh kg(-1) at a power density of similar to 21 kW kg(-1). The excellent capacitance retention and electrochemical stability of the flexible RuO2/Gr/Cu electrode are due to the improved mechanical adhesion between the RuO2 and the current collector. This flexible RuO2/Gr/Cu film could be used as a supercapacitor electrode with a high capacity and long-cycle life for the next-generation flexible electronic applications. (C) 2017 Elsevier B.V. All rights reserved.