• 文献标题:   Preparation of Highly Conductive Graphene Hydrogels for Fabricating Supercapacitors with High Rate Capability
  • 文献类型:   Article
  • 作  者:   ZHANG L, SHI GQ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   529
  • DOI:   10.1021/jp204036a
  • 出版年:   2011

▎ 摘  要

Graphene hydrogels prepared via hydrothermal reduction of graphene oxide dispersions (GH-Hs) were further reduced with hydrazine (Hz) or hydroiodic acid (HI) to improve their conductivities. The chemically reduced graphene hydrogels possess high conductivities of 1.3-3.2 S m(-1), which are 1 order of magnitude higher than that of a GH-H (0.3 S m(-1)). The supercapacitor based on the Hz-reduced GH-H exhibited a high specific capacitance of 220 F g(-1) at 1 A g(-1), and this capacitance can be maintained for 74% as the discharging current density was increased up to 100 A g(-1). Furthermore, it showed high power density and long cycle life. The high-performances of this supercapacitor make it promising for high rate charge/discharge applications.