• 文献标题:   Polyaniline/alpha-Ni(OH)(2)/iron oxide-doped reduced graphene oxide-based hybrid electrode material
  • 文献类型:   Article
  • 作  者:   DAS AK, MAITRA A, KARAN SK, BERA R, PARIA S, KHATUA BB
  • 作者关键词:   supercapacitor, oxidative polymerization, specific capacitance, energy density
  • 出版物名称:   JOURNAL OF APPLIED ELECTROCHEMISTRY
  • ISSN:   0021-891X EI 1572-8838
  • 通讯作者地址:   Indian Inst Technol Kharagpur
  • 被引频次:   6
  • DOI:   10.1007/s10800-017-1052-7
  • 出版年:   2017

▎ 摘  要

In this study, the electrochemical performance of a polyaniline-based porous ternary composite (PNHFeG) electrode material is reported for a high-performance supercapacitor. The PNHFeG ternary composite was prepared through in situ oxidative polymerization of aniline in the presence of a binary composite NHFeG that involves the combination of flower-like nanostructured Ni(OH)(2) and iron oxide-doped reduced graphene oxide (Fe-RGO). The porous ternary PNHFeG composite with high surface area (239 m(2) g(-1)) notably exhibits maximum specific capacitance (C (sp) ) of 2714 F g(-1) at 5 A g(-1) current density, along with 98.5% retention of its initial capacitance even after 2000 cycles. Moreover, even at a higher current density of 30 A g(-1), the composite electrode material maintains a remarkable C (sp) value of 1223 F g(-1). Finally, the PNHFeG electrode material reveals a power density of 1498 W kg(-1), along with a maximum energy density of 135.7 Wh kg(-1) at 5 A g(-1), suggesting that the current composite electrode material can be considered as a promising candidate for high-performance supercapacitor applications.