• 文献标题:   Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer
  • 文献类型:   Article
  • 作  者:   DUAN FF, CHEN CQ, WANG GZ, YANG YZ, LIU XG, QIN Y
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Taiyuan Univ Technol
  • 被引频次:   39
  • DOI:   10.1039/c3ra45354e
  • 出版年:   2014

▎ 摘  要

Molecularly imprinted polymers on GO nanosheets (MIPs/GO) for desulfurization are synthesized using dibenzothiophene (DBT) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker. The formation of this hybrid material is verified by Fourier transform infrared spectroscopy, thermal gravimetric and atomic force microscopy analysis. The adsorption results show that the prepared MIPs/GO exhibit excellent adsorption capacity (up to 181.9 mg g(-1) at 298 K) and fast mass transfer and binding kinetics for DBT. The kinetics and isotherm data can be well described by the pseudo-first-order kinetic model and the Freundlich isotherm, respectively. Competitive adsorption experiments demonstrate that MIPs/GO show higher affinity toward target molecule DBT than toward structural analogue benzothiophene.