• 文献标题:   Simple preparation of reduced graphene oxide coatings for solid phase micro-extraction (SPME) of furfural to be detected by gas chromatography/mass spectrometry
  • 文献类型:   Article
  • 作  者:   PINEIROGARCIA A, GONZALEZALATORRE G, TRISTAN F, FIERROGONZALEZ JC, VEGADIAZ SM
  • 作者关键词:   graphene oxide coating, solid phase microextraction, furfural
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Inst Tecnol Celaya
  • 被引频次:   5
  • DOI:   10.1016/j.matchemphys.2018.04.057
  • 出版年:   2018

▎ 摘  要

Graphene oxide is widely-used for many applications because of its surface area and the variety of oxygen functional groups that possess. This latter feature allows it to be a good candidate for polar compounds adsorption such as furfural. Furfural is a toxic compound that has been detected in a wide variety of foods of daily consumption. Frequent exposure in high doses can represent a risk to human health. In the present work, it is proposed an easy procedure to obtain reduced graphene oxide based coatings through dip-coating for Solid Phase Micro-Extraction (SPME) of furfural. The coatings were made with graphene oxide and carboxylated graphene oxide. These coatings were thermally reduced and then tested using a furfural standard. The thermally reduced graphene oxide coatings were characterized using FT-IR, Raman spectroscopy and SEM. SEM micrographs revealed that graphene oxide based fibers had thickness values between 1.5 and 2.5 mu m approximately. Subsequently the results of furfural extraction were compared with those obtained from the Divinylbenzene/Carboxen/Polydimethylsiloxane (DVB/CAR/PDMS) commercial fibers. (C) 2018 Elsevier B.V. All rights reserved.