• 文献标题:   A comparative study of graphene materials formed by thermal exfoliation of graphite oxide and chlorine trifluoride-intercalated graphite
  • 文献类型:   Article
  • 作  者:   SHUL GA YM, LOBACH AS, BASKAKOV SA, SPITSYNA NG, MARTYNENKO VM, RYZHKOV AV, SOKOLOV VB, MASLAKOV KI, DEMENT EV AP, ELETSKII AV, KAZAKOV VA, SIGALAEV SK, RIZAKHANOV RN, SHUL GA NY
  • 作者关键词:  
  • 出版物名称:   HIGH ENERGY CHEMISTRY
  • ISSN:   0018-1439 EI 1608-3148
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   6
  • DOI:   10.1134/S001814391306009X
  • 出版年:   2013

▎ 摘  要

Graphene 3D materials GM1 and GM2 obtained by explosive exfoliation of graphite oxide and graphite intercalated with chlorine trifluoride, respectively, have been studied by elemental analysis, X-ray photoelectron spectroscopy, mass spectrometry, infrared and Raman spectroscopy, and scanning electron microscopy. The specific surface area, the pore size, and electrical conductivity of the materials have been measured. A comparative study has shown that the gas mixture produced during the preparation of GM1 is less hazardous than that in the case of GM2. However, GM2 exhibits a higher conductivity and a larger size of graphene crystallites. The feasibility of isolation of a suspension of graphene nanosheets from the test 3D materials has been demonstrated. Possible applications of these materials are discussed.