• 文献标题:   Facile synthesis of reduced graphene oxide-modified, nitrogen-doped carbon xerogel with enhanced electrochemical capacitance
  • 文献类型:   Article
  • 作  者:   LEI G, HU XY, PENG ZG, HU JW, LIU HT
  • 作者关键词:   reduced graphene oxide, hydrothermal treatment, carbon xerogel, electrochemical capacitance
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   6
  • DOI:   10.1016/j.matchemphys.2014.09.042
  • 出版年:   2014

▎ 摘  要

In this contribution, we report a reduced graphene oxide (rGO)-modified nitrogen-doped carbon xerogel, which could be easily prepared by pyrolysis of melamine-formaldehyde (MF) resins that are polymerized hydrothermally in an aqueous GO dispersion. Scanning electron microscopy, transmission electron microscopy, Fourier-transformed infrared spectrometry, and nitrogen adsorption-desorption method were employed to reveal the morphologies and structures of the prepared carbon xerogel. Cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge-discharge were used to investigate the electrochemical properties. The results showed that the charge transfer barrier of the mesoporous nitrogen-doped carbon xerogel was decreased evidently, owing to the modification of a layer of rGO on its wall, and the xerogel demonstrated a capacitance of as high as 205 F g(-1) at the current of 1 A g(-1). (C) 2014 Elsevier B.V. All rights reserved.