• 文献标题:   Strain-Engineered Graphene Grown on Hexagonal Boron Nitride by Molecular Beam Epitaxy
  • 文献类型:   Article
  • 作  者:   SUMMERFIELD A, DAVIES A, CHENG TS, KOROLKOV VV, CHO YJ, MELLOR CJ, FOXON CT, KHLOBYSTOV AN, WATANABE K, TANIGUCHI T, EAVES L, NOVIKOV SV, BETON PH
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Univ Nottingham
  • 被引频次:   26
  • DOI:   10.1038/srep22440
  • 出版年:   2016

▎ 摘  要

Graphene grown by high temperature molecular beam epitaxy on hexagonal boron nitride (hBN) forms continuous domains with dimensions of order 20 mu m, and exhibits moire patterns with large periodicities, up to similar to 30 nm, indicating that the layers are highly strained. Topological defects in the moire patterns are observed and attributed to the relaxation of graphene islands which nucleate at different sites and subsequently coalesce. In addition, cracks are formed leading to strain relaxation, highly anisotropic strain fields, and abrupt boundaries between regions with different moire periods. These cracks can also be formed by modification of the layers with a local probe resulting in the contraction and physical displacement of graphene layers. The Raman spectra of regions with a large moire period reveal split and shifted G and 2D peaks confirming the presence of strain. Our work demonstrates a new approach to the growth of epitaxial graphene and a means of generating and modifying strain in graphene.