• 文献标题:   Enhanced Adsorptions to Polysulfides on Graphene-Supported BN Nanosheets with Excellent Li-S Battery Performance in a Wide Temperature Range
  • 文献类型:   Article
  • 作  者:   DENG DR, XUE F, BAI CD, LEI J, YUAN RM, SEN ZHENG M, DONGO QF
  • 作者关键词:   high temperature, low temperature, synergistic effect, lis battery, enhanced adsorption
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   iChem Collaborat Innovat Ctr Chem Energy Mat
  • 被引频次:   12
  • DOI:   10.1021/acsnano.8b05534
  • 出版年:   2018

▎ 摘  要

For Li-S batteries, the catalysis for S redox reaction is indispensable. A lot of multifunctional sulfur electrode support materials with have been investigated widely. However, most of these studies were carried out. at room temperature, and the interaction between different components in the matrix is not often paid enough attention. Here, we report a graphene supported BN nanosheet composite in which the synergistic effect between BN and graphene greatly enhanced the adsorption for polysulfides, thus leading to excellent performance in a wide temperature range. When used as a host material of sulfur, it can make the Li-S battery apply to a wide range of temperatures, from -40 to 70 degrees C, delivering a high utilization of sulfur, an excellent rate capability, and outstanding cycling life. The capacity can stabilized at 888 mAh g(-1) at 2 C after 300 cycles with a capacity attenuation of <0.04% per cycle at 70 degrees C, and the battery can deliver a capacity above 650 mAh g(-1) at 40 degrees C.