• 文献标题:   Stability and Tribological Performance of Nanostructured 2D Turbostratic Graphite and Functionalised Graphene as Low-Viscosity Oil Additives
  • 文献类型:   Article
  • 作  者:   LAU GA, NEVES GO, SALVARO DB, BINDER C, KLEIN AN, DE MELLO JDB
  • 作者关键词:   2d graphite, graphene, suspension stability, lubrication, tribology
  • 出版物名称:   LUBRICANTS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/lubricants11040155
  • 出版年:   2023

▎ 摘  要

The dispersion stability of carbon-based solid lubricants/lubricating oils remains a challenge to overcome. Recently, novel processing routes were developed to obtain 2D turbostratic graphite particles via solid-state reactions between B4C and Cr3C2 (GBC) and between SiC and Fe (GSF) that present outstanding tribological properties in a dry scenario, as well as functionalized graphene (GNH). This work investigated the suspension stability of GBC and GSF particles (0.05 wt.%) dispersed in a low-viscosity polyol ester lubricating oil and their tribological performance. Ammonia-functionalized graphene (GNH) particles were also used as a reference. In order to evaluate the dispersion stability, in addition to the classical digital image technique, a much more assertive, reliable, quantitative and rarely reported in the literature technique was used, i.e., the STEPTM (Space and Time-resolved Extinction Profiles) technology. Reciprocating sphere-on-flat tribological tests were carried out, in which before contact, 0.2 mu L of pure oil and suspension (POE + 0.05 wt.% of solid lubricant) was applied on a flat surface. The results showed that the GBC particles remained remarkably stable and reduced the sphere wear rate by 61.8%. From the tribosystem point of view, the presence of GBC and GSF reduced the wear rate by 18.4% and 2.2%, respectively, with respect to the pure oil, while the GNH particles increased the wear rate by 4.2%. Furthermore, the wear rate was improved due to the highly disordered carbon tribolayer formation identified on both surfaces.