• 文献标题:   Strong and Stable Doping of Carbon Nanotubes and Graphene by MoOx for Transparent Electrodes
  • 文献类型:   Article
  • 作  者:   HELLSTROM SL, VOSGUERITCHIAN M, STOLTENBERG RM, IRFAN I, HAMMOCK M, WANG YB, JIA CC, GUO XF, GAO YL, BAO ZN
  • 作者关键词:   transparent conductor, nanotube, composite, doping
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Stanford Univ
  • 被引频次:   97
  • DOI:   10.1021/nl301207e
  • 出版年:   2012

▎ 摘  要

MoOx has been used for organic semiconductor doping, but it had been considered an inefficient and/or unstable dopant. We report that MoOx can strongly and stably dope carbon nanotubes and graphene. Thermally annealed MoOx-CNT composites can form durable thin film electrodes with sheet resistances of 100 Omega/sq at 85% transmittance plain and 85 Omega/sq at 83% transmittance with a PEDOT:PSS adlayer. Sheet resistances change less than 10% over 20 days in ambient and less than 2% with overnight heating to 300 degrees C in air. The MoOx can be easily deposited either by thermal evaporation or from solution-based precursors. Excellent stability coupled with high conductivity makes MoOx-CNT composites extremely attractive candidates for practical transparent electrodes.