• 文献标题:   Self-assembly of a CoFe2O4/graphene sandwich by a controllable and general route: towards a high-performance anode for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   LIU SY, XIE J, FANG CC, CAO GS, ZHU TJ, ZHAO XB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   100
  • DOI:   10.1039/c2jm34019d
  • 出版年:   2012

▎ 摘  要

A CoFe2O4-nanocrystal/ graphene-nanosheet (CFO/GS) nanohybrid has been synthesized by a facile in situ solvothermal route and has been investigated as a promising high-performance anode material for Li-ion batteries. The crystal size of CoFe2O4 can be controlled to 10-20 nm by pre-treating the precursors before the solvothermal reactions. The method for synthesizing the CFO/GS hybrid can be extended to synthesize MFe2O4/graphene (MFe2O4/G, M = Mn and Ni) hybrids. The CFO/GS hybrid exhibits superior cycling stability and rate capability compared to bare CoFe2O4. The improved electrochemical performance can be attributed to a combination of the conducting, confining and dispersing effects of graphene.