• 文献标题:   Enhanced photoluminescence quantum yield of MAPbBr(3) nanocrystals by passivation using graphene
  • 文献类型:   Article
  • 作  者:   PARK Y, JANA A, MYUNG CW, YOON T, LEE GS, KOCHER CC, YING GH, OSOKIN V, TAYLOR RA, KIM KS
  • 作者关键词:   perovskite nanocluster, photoluminescence, surface passivation, graphene, density functional theory calculation
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Ulsan Natl Inst Sci Technologh
  • 被引频次:   2
  • DOI:   10.1007/s12274-020-2718-8
  • 出版年:   2020

▎ 摘  要

Diminishing surface defect states in perovskite nanocrystals is a highly challenging subject for enhancing optoelectronic device performance. We synthesized organic/inorganic lead-halide perovskite MAPbBr(3) (MA = methylammonium) clusters comprising nanocrystals with diameters ranging between 20-30 nm and characterized an enhanced photoluminescence (PL) quantum yield (as much as ~ 7 times) by encapsulating the MAPbBr(3) with graphene (Gr). The optical properties of MAPbBr(3) and Gr/MAPbBr(3) were investigated by temperature-dependent micro-PL and time-resolved PL measurements. Density functional theory calculations show that the surface defect states in MAPbBr(3) are removed and the optical band gap is reduced by a 0.15 eV by encapsulation with graphene due to partial restoration of lattice distortions.