• 文献标题:   Near-Infrared Photoluminescence in the Femtosecond Time Region in Mono layer Graphene on SiO2
  • 文献类型:   Article
  • 作  者:   KOYAMA T, ITO Y, YOSHIDA K, TSUJI M, AGO H, KISHIDA H, NAKAMURA A
  • 作者关键词:   monolayer graphene, photocarrier relaxation, carrier cooling dynamic, carrierphonon interaction, photoluminescence, femtosecond timeresolved luminescence spectroscopy
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Nagoya Univ
  • 被引频次:   14
  • DOI:   10.1021/nn305558r
  • 出版年:   2013

▎ 摘  要

We Investigate the dynamical properties of photoexcited carders In a single monolayer of graphene at room temperature in air using femtosecond time-resolved luminescence spectroscopy. The luminescence kinetics are observed in the near-Infrared region of 0.7-1.4 eV and analyzed based on the two-temperature model describing the cooling of thermalized carriers via the carrier-optical phonon Interaction. The observed luminescence In the range 0.7-0.9 eV is well reproduced by the model. In the range 1.0-1.4 eV, however, the luminescence, which decays in similar to 300 fs, cannot be reproduced by this model. These results indicate that the carrier system is not completely thermalized in similar to 300 fs. We also show the importance of the carrier-doping effect Induced by the substrate and surrounding environment in the carrier cooling dynamics and the predominance of optical phonons over acoustic phonons In the carrier-phonon interactions even at a temperature of similar to 400 K.