• 文献标题:   Designing a new ligand based on pyridine for immobilization of gold nanoparticles on reduced magnetic graphene oxide: a new catalyst for the reduction of nitro compounds
  • 文献类型:   Article, Early Access
  • 作  者:   MOGHADDAM FM, SIAHPOOSH A, ESLAMI M
  • 作者关键词:   gold nanoparticle, reduced graphene oxide, heterogeneous catalysi, supported catalyst, nitroarene
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s13738-022-02673-x EA OCT 2022
  • 出版年:   2022

▎ 摘  要

We present a novel pincer ligand based on the pyridine scaffold for functionalizing magnetic GO (graphene oxide). Pincer ligands are known for their great control of coordination spheres in catalysts. GO is used as solid support for immobilizing gold nanoparticles to synthesize a heterogeneous catalyst for reducing nitroarenes. The reduction of nitroarenes to aromatic amines is not only of environmental importance but can be used as a model reaction too. The yields of the reduction reactions are promising. Additionally, the reaction conditions are mild and the catalyst has good recyclability and great stability. The nanocatalyst was monitored and characterized by spectroscopic methods.