• 文献标题:   High-Performance All-solid-state microsupercapacitors from 3D printing Structure-engineered Graphene-Carbon sphere electrodes
  • 文献类型:   Article
  • 作  者:   ZHANG Y, SONG YY, SHI Y, WANG YL, WANG XX, SHI XW, TANG C, LIU JM, WANG GL, TAN Q, LI L
  • 作者关键词:   microsupercapacitor, 3d printing, graphene ink, areal energy density, structure engineering
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.apsusc.2022.153730 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

The improvement of the areal energy density of graphene-based microsupercapacitors (MSCs) is reduced by the graphene aggregation issue in electrodes. Solving this issue in MSCs can enhance their electrochemical performance and facilitate their applications in microdevices. Herein, we experimentally realize to prevent graphene aggregation in electrode by engineering its structure via combing both strategies of the addition of spacers of carbon sphere and self-sacrificing template of ethyl cellulose during the 3D printing process. The MSCs based on these electrodes deliver good electrochemical performance with high energy density (4.17 mu Wh cm(-2)) and power density (0.22 mW cm(-2)), promising cycling performance and mechanical flexibility. The method developed here provides a paradigm for preparing high-performance MSCs.