• 文献标题:   Schiff base complexes of Mo(VI) immobilized on functionalized graphene oxide nano-sheets for the catalytic epoxidation of alkenes
  • 文献类型:   Article
  • 作  者:   REZAZADEH B, POURALI AR, BANAEI A, BEHNIAFAR H
  • 作者关键词:   mo vi schiff base complexe, graphene oxide, alkene epoxidation, heterogeneous catalyst
  • 出版物名称:   JOURNAL OF COORDINATION CHEMISTRY
  • ISSN:   0095-8972 EI 1029-0389
  • 通讯作者地址:   Damghan Univ
  • 被引频次:   0
  • DOI:   10.1080/00958972.2019.1691724 EA NOV 2019
  • 出版年:   2019

▎ 摘  要

Mo(VI) tetradentate Schiff base complexes were covalently immobilized onto chemically functionalized graphene oxide (GO) using 3-(tri-methoxysilyl) propylamine as a coupler. The resulting heterogeneous catalysts have been characterized by FTIR, DRS, XRD, SEM, TGA, and atomic absorption spectroscopy (AAS). These catalysts were applied in epoxidation of cyclooctene and other olefins. The catalytic procedures with all catalysts were optimized for different parameters such as oxidant, solvent and temperature. Recycling results indicated that the catalysts were highly stable and maintained activity and selectivity even after being used for five cycles.