• 文献标题:   One-Pot Rapid Synthesis of Mo(S,Se)(2) Nanosheets on Graphene for Highly Efficient Hydrogen Evolution
  • 文献类型:   Article
  • 作  者:   NAKAYASU Y, YASUI Y, TANIKI R, OIZUMI K, KOBAYASHI H, NAGAMURA N, TOMAI T, HONMA I
  • 作者关键词:   hydrogen evolution reaction, supercritical fluid, molybdenum dichalcogenide, solidsolution, graphene
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   7
  • DOI:   10.1021/acssuschemeng.8b01614
  • 出版年:   2018

▎ 摘  要

The electrocatalytic hydrogen evolution reaction (HER) is known to be an important technique for efficient hydrogen production, and the development of a highly active electrocatalyst with lower overpotential is a key issue. In this study, we demonstrated the rapid, one-pot synthesis of highly active molybdenum dichalcogenide/reduced graphene oxide (Mo(S,Se)/rGO) electrocatalysts from cost-effective and environmentally friendly substances using reductive supercritical conditions. We found that edge-rich MoS2 is synthesized under a high-density ethanol condition and successfully controlled the composition of molybdenum dichalcogenide (MoS2-xSex) nanoflowers at the atomic level by varying the ratio of chalcogen sources. The electrocatalytic HER activity increased with the formation of an edges-rich structure and a solid solution of MoS2 and MoSe2, and by complexing with graphene. The synthesized MoS0.9Se1.1/graphene showed excellent HER properties that can be categorized into the highest-activity group of the previously reported molybdenum dichalcogenide and its composite. Such high electrocatalytic HER performance should be the result of optimizing the hydrogen adsorption free energy of MoS2-xSex and effectively forming conductive paths between MoS0.9Se1.1 and graphene. This rapid one-pot process using supercritical ethanol will be suitable for the mass production of highly active molybdenum dichalcogenide electrocatalysts.