• 文献标题:   Adsorption behavior of NO2 molecules in ZnO-mono/multilayer graphene core-shell quantum dots for NO2 gas sensor
  • 文献类型:   Article
  • 作  者:   LEE KS, SHIM J, LEE JS, LEE J, MOON HG, PARK YJ, PARK D, SON DI
  • 作者关键词:   zno qd, graphene, coreshell qd, gas sensor, surface potential
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1016/j.jiec.2021.11.003 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

We demonstrated the sensing properties and adsorption mechanism of NO2 molecules of monolayer graphene and multilayer graphene encapsulated ZnO QDs for NO2 gas adsorption. The gas response value of ZnO-multilayer graphene (ZMLG) QDs was approximately 23 % and 7.2 and 25.5 times higher than that with ZnO-monolayer graphene (ZG) and ZnO QDs, respectively. The surface potential change of ZMLG QDs increased up to 14.25 times compared to ZnO QDs and 6.33 times increased compared to ZG QDs. We proposed an accurate adsorption mechanism for the improvement of the detection behavior that is occured by covering the graphene shells into ZnO QDs by the Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), and SKPM measurement. These results are expected to increase the accuracy of gas sensor characteristic analysis. (c) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.