• 文献标题:   Transition metal oxide and graphene nanocomposites for high-performance electrochemical capacitors
  • 文献类型:   Article
  • 作  者:   ZHANG WF, LIU F, LI QQ, SHOU QL, CHENG JP, ZHANG L, NELSON BJ, ZHANG XB
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   70
  • DOI:   10.1039/c2cp43673f
  • 出版年:   2012

▎ 摘  要

A method for producing nanocomposites of transition metal oxides A(3)O(4) (where A represents Mn, Fe or Co) and graphene nanosheets (GNS) is presented. The reduction of graphene oxide (GO) and the formation of A(3)O(4) nanoparticles (NPs) were carried out simultaneously during the reaction. The electrochemical properties of A(3)O(4)-GNS nanocomposites as electrode materials for supercapacitors are investigated by cyclic voltammetry and galvanostatic charge-discharge tests. specific capacitance (708, 358 and 240 F g(-1), respectively), high energy density (20, 10 and 7 W h kg(-1), respectively) and good electrochemical stability (retention of 73%, 67.8% and 95.8%, respectively, after 1000 charge-discharge cycles). The excellent electrochemical performance of the A(3)O(4)-graphene nanocomposites indicates great potential in the application in commercial supercapacitors.