• 文献标题:   Ultrasensitive voltammetric detection of benzenediol isomers using reduced graphene oxide-azo dye decorated with gold nanoparticles
  • 文献类型:   Article
  • 作  者:   ALSHIK NMM, SULAIMAN Y
  • 作者关键词:   electrochemical sensor, reduced graphene oxide, procion red mx5b, gold nanoparticle, simultaneous detection
  • 出版物名称:   ECOTOXICOLOGY ENVIRONMENTAL SAFETY
  • ISSN:   0147-6513 EI 1090-2414
  • 通讯作者地址:   Univ Putra Malaysia
  • 被引频次:   0
  • DOI:   10.1016/j.ecoenv.2020.111026
  • 出版年:   2020

▎ 摘  要

The detection of phenolic compounds, i.e. resorcinol (RC) catechol (CC) and hydroquinone (HQ) are important due to their extremely hazardous impact and poor environmental degradation. In this work, a novel and sensitive composite of electrochemically reduced graphene oxide-poly(Procion Red MX-5B)/gold nanoparticles modified glassy carbon electrode (GCE/ERGO-poly(PR)/AuNPs) was assembled for voltammetric detection of benzenediol isomers (RC, CC, and HQ). The nanocomposite displayed high peak currents towards the oxidation of RC, HQ, and CC compared to non-modified GCE. The peak-to-peak separations were 0.44 and 0.10 V for RC-CC and CC-HQ, respectively. The limit of detections were 53, 53, and 79 nM for HQ, CC, and RC with sensitivities of 4.61, 4.38, and 0.56 mu A/mu M (S/N 1/4 3), respectively. The nanocomposite displayed adequate reproducibility, besides good stability and acceptable recoveries for wastewater and cosmetic samples analyses.