• 文献标题:   Impact of the Density and Oxygen Concentration of Initial Amorphous Carbon on Layer Exchange of Multilayer Graphene
  • 文献类型:   Article
  • 作  者:   MURATA H, TOKO K, MURAKAMI K, NAGAO M
  • 作者关键词:  
  • 出版物名称:   CRYSTAL GROWTH DESIGN
  • ISSN:   1528-7483 EI 1528-7505
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acs.cgd.2c01083 EA NOV 2022
  • 出版年:   2022

▎ 摘  要

Layer exchange (LE) of amorphous carbon (a-C) is a promising method for fabricating high-quality multilayer graphene (MLG) on insulating substrates. We investigated the effects of initial a-C properties on the growth temperature and crystal quality of LE-MLG by controlling the a-C sputtering pressure (Pa-C). X-ray reflectivity and X-ray photoelectron spectroscopy revealed that the a-C density decreased and the O concentration in the a-C film increased with increasing Pa-C. LE occurred at the lowest temperature of 600 degrees C, reflecting a lower density and O concentration of a-C. Raman spectroscopy results showed that the crystal quality of LE-MLG improved with increasing Pa-C. Based on our results, we developed guidelines for the a-C properties in the LE technique to reduce the growth temperature and improve the crystal quality of MLG.