• 文献标题:   Porous graphene prepared from anthracite as high performance anode materials for lithium-ion battery applications
  • 文献类型:   Article
  • 作  者:   XING BL, ZENG HH, HUANG GX, ZHANG CX, YUAN RF, CAO YJ, CHEN ZF, YU JL
  • 作者关键词:   coalbased porous graphene, anode material, lithium ion batterie, electrochemical performance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Henan Polytech Univ
  • 被引频次:   20
  • DOI:   10.1016/j.jallcom.2018.11.288
  • 出版年:   2019

▎ 摘  要

Porous graphene has attracted considerable attention for its promising potential application in energy storage devices due to its unique porous structure combined with inherent electronic characteristics of graphene. Herein, a cost effective and environmentally friendly strategy is developed to prepare porous graphene via graphitization coupled with liquid oxidation-rapid thermal reduction using anthracite as a precursor. The prepared porous graphene has microstructure features such as highly continuous corrugated nanosheets with micro-meso-macro hierarchical porous structure, high specific surface area (640 m(2)g(-1)) and large pore volume (3.792 cm(3)g(-1)) with large amount of structural defects and nano-pores, which provides sufficient active sites for lithium ions storage and offers favorable pathways for the fast transportation of lithium ions and electrons. When used as anode materials for lithium-ion batteries, such porous graphene exhibits a high reversible capacity of 770 mAh . g(-1) at current density of 0.1 C, and possesses an outstanding rate capability with desirable capacities of 274 mAh . g(-1) and 224 mAh . g(-1) even at high current densities of 10 C and 20 C. Moreover, such porous graphene also demonstrates superior cycling performance up to 98.0% of the initial reversible capacity retention after 110 cycles. This study paves a promising approach to the large-scale production of porous graphene from coal for high performance anode materials used in lithium-ion batteries. (C) 2018 Elsevier B.V. All rights reserved.