• 文献标题:   A reagentless non-enzymatic hydrogen peroxide sensor presented using electrochemically reduced graphene oxide modified glassy carbon electrode
  • 文献类型:   Article
  • 作  者:   MUTYALA S, MATHIYARASU J
  • 作者关键词:   electrochemically reduced graphene oxide, hydrogen peroxide, nonenzymatic, electrocatalytic reduction, electrochemical biosensor
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING CMATERIALS FOR BIOLOGICAL APPLICATIONS
  • ISSN:   0928-4931 EI 1873-0191
  • 通讯作者地址:   Acad Sci Innovat Res AcSIR
  • 被引频次:   35
  • DOI:   10.1016/j.msec.2016.06.069
  • 出版年:   2016

▎ 摘  要

Herein, We report a simple, facile and reproducible non-enzymatic hydrogen peroxide (H2O2) sensor using electrochemically reduced graphene oxide (ERGO) modified glassy carbon electrode (GCE). The modified electrode was characterized by Fourier transform infrared (FT-IR), UV-Visible, scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. Cyclic voltammetric (CV) analysis revealed that ERGO/GCE exhibited virtuous charge transfer properties for a standard redox systems and showed excellent performance towards electroreduction of H2O2. Amperometric study using ERGO/GCE showed high sensitivity (0.3 mu A/mu M) and faster response upon the addition of H2O2 at an applied potential of -0.25 V vs. Ag/AgCl. The detection limit is assessed to be 0.7 mu M (S/N = 3) and the time to reach a stable study state current is <3 s for a linear range of H2O2 concentration (1-16 mu M). In addition, the modified electrode exhibited good reproducibility and long-term stability. (C) 2016 Elsevier B.V. All rights reserved.