• 文献标题:   A Simple Route to Reduced Graphene Oxide-Draped Nanocomposites with Markedly Enhanced Visible-Light Photocatalytic Performance
  • 文献类型:   Article
  • 作  者:   LIU XQ, YANG JB, ZHAO W, WANG Y, LI Z, LIN ZQ
  • 作者关键词:  
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   China Univ Geosci
  • 被引频次:   18
  • DOI:   10.1002/smll.201601110
  • 出版年:   2016

▎ 摘  要

Nanocomposites (denoted RGO/ZnONRA) comprising reduced graphene oxide (RGO) draped over the surface of zinc oxide nanorod array (ZnONRA) were produced via a simple low-temperature route, dispensing with the need for hydrothermal growth, electrochemical deposition or other complex treatments. The amount of deposited RGO can be readily tuned by controlling the concentration of graphene oxide (GO). Interestingly, the addition of Sn2+ not only enables the reduction of GO, but also functions as a bridge that connects the resulting RGO and ZnONRA. Remarkably, the incorporation of RGO improves the visible-light absorption and reduces the bandgap of ZnO, thereby leading to the markedly improved visible-light photocatalytic performance. Moreover, RGO/ZnONRA nanocomposites exhibit a superior stability as a result of the surface protection of ZnONRA by RGO. The mechanism on the improved photocatalytic performance based on the cophotosensitizations under the visible-light irradiation has been proposed. This simple yet effective route to the RGO-decorated semiconductor nanocomposites renders the better visible-light utilization, which may offer great potential for use in photocatalytic degradation of organic pollutants, solar cells, and optoelectronic materials and devices.