• 文献标题:   Ion assisted anchoring Sn nanoparticles on nitrogen-doped graphene as an anode for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   ZHAN L, ZHOU XS, LUO J, NING XM
  • 作者关键词:   sn, graphene, lithium ion batterie, 7 7 8 8tetracyanoquinodimethane
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Lingnan Normal Univ
  • 被引频次:   3
  • DOI:   10.1016/j.ijhydene.2019.07.153
  • 出版年:   2019

▎ 摘  要

Though lithium ion batteries are popular in many fields, high performance electrode materials with reasonable structure are desired. Herein, Sn/nitrogen-doped graphene (NGN) was fabricated with the help of 7,7,8,8-tetracyanoquinodimethane anion (TCNQ center dot(-)). TCNQ center dot(-) was used to anchor Sn4+ into the graphene layer with the electrostatic interaction, which improves the distribution of Sn nanoparticles. Meanwhile, TCNQ center dot(-) acts as a nitrogen source to construct N doped graphene, enhancing the electron conductivity of the composite. Benefiting from the strong structure and good ion/electron conductivity, the Sn/ NGN composite achieved excellent electrochemical battery performance. At high rates of 1 and 2 A g(-1), capacities of 433 and 353 mA h g(-1) were acquired, respectively. Moreover, the Sn/NGN composite outputted a high capacity of 584 mA h g(-1) at the end of 1000 cycles at 1 A g(-1). (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.