• 文献标题:   Hierarchical dandelion-like copper oxide wrapped by reduced graphene oxide: Hydrothermal synthesis and their application in supercapacitors
  • 文献类型:   Article
  • 作  者:   LIU AF, BAI YM, LIU YM, ZHAO MS, MU JB, WU CX, ZHANG XL, WANG GS, CHE HW
  • 作者关键词:   oxide, composite, nanostructure, chemical synthesi, electrochemical propertie
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Hebei Univ Engn
  • 被引频次:   11
  • DOI:   10.1016/j.materresbull.2016.07.034
  • 出版年:   2016

▎ 摘  要

In this study, reduced graphene oxide (rGO)-wrapped dandelion-like CuO microspheres have been successfully synthesized using a one-step hydrothermal method without calcination. Characterization results demonstrate that dandelion-like CuO microspheres with sizes of 2.0 mu m are well wrapped by ultrathin rGO nanosheets. Moreover, the introduced amount of GO dispersion in the reaction system was found to play a key role in tuning the phase compositions and microstructures of the resultant CuO-rGO composites. When used as electrode materials for supercapacitors, dandelion-like CuO wrapped by rGO nanosheets exhibited the best capacitive behavior with a specific capacitance of 296 F g(-1) at 1.0 A g(-1) and a retention of 96.1% after 2000 cycles at 2.0 Ag-1. Such excellent electrochemical performance might be mainly attributed to the rGO wrapping effect, efficiently providing higher electronic conductivity and buffering the volume changes. (C) 2016 Elsevier Ltd. All rights reserved.