• 文献标题:   1D Cu@Ni nanorods anchored on 2D reduced graphene oxide with interfacial engineering to enhance microwave absorption properties
  • 文献类型:   Article
  • 作  者:   ZHAO BA, LIANG LY, DENG JS, BAI ZY, LIU JW, GUO XQ, GAO K, GUO WH, ZHANG R
  • 作者关键词:  
  • 出版物名称:   CRYSTENGCOMM
  • ISSN:   1466-8033
  • 通讯作者地址:   Zhengzhou Univ Aeronaut
  • 被引频次:   28
  • DOI:   10.1039/c7ce01439b
  • 出版年:   2017

▎ 摘  要

In this work, one-dimensional core-shell Cu@Ni nanorods which were anchored on two dimensional reduced graphene oxide (rGO) heterostructures were successfully prepared by a simple co-reduction method. The characteristics of Cu@Ni/rGO composites were measured and collected by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. The formation mechanisms of these unique Cu@Ni nanorods-rGO heterostructures were discussed in detail. Compared with pure Cu@Ni and rGO, the Cu@Ni/rGO composite showed strong microwave absorption performance with a minimal reflection loss value of -41.2 dB at 8.8 GHz. The excellent microwave absorption properties could be attributed to the suitable impedance match, eddy current loss, multiple reflection and intense interfacial polarization of multiple interfaces existing in Ni/Cu, Cu@Ni/rGO, Ni/rGO, and Cu/rGO systems. The effective bandwidth with a reflection loss lower than -10 dB can be tuned in a frequency range of 3.8-18 GHz with an absorber thickness of 1.0-4.0 mm. This proves that the Cu@Ni/rGO heterostructure is a promising candidate as a highly efficient and lightweight absorber in C (4-8 GHz), X (8-12 GHz) and Ku (12-18 GHz) bands.