• 文献标题:   Porous nitrogen-doped graphene for high energy density supercapacitors in an ionic liquid electrolyte
  • 文献类型:   Article
  • 作  者:   LIU D, FU CP, ZHANG NS, LI YL, ZHOU HH, KUANG YF
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   5
  • DOI:   10.1007/s10008-016-3431-0
  • 出版年:   2017

▎ 摘  要

Porous nitrogen-doped graphene (PNG) has been prepared via simple thermal treatment of graphene oxide and urea, and the morphology and structure of the PNG have been characterized by using a range of electron microscopy, X-ray photoelectron spectroscopy, and other techniques. The electrochemical performances of the PNG have been investigated in an ionic liquid electrolyte by cyclic voltammetry and galvanostatic charge-discharge via both three-electrode and two-electrode configurations. The PNG electrode delivers a specific capacitance of 310 F g(-1) at 1 A g(-1) with good cycling stability over 4000 cycles. The high electrochemical performance is ascribed to the porous structure and nitrogen-doping in the PNG. The porous structure enables high specific surface area and rapid ion mobility, contributing to double layer capacitance, while the N-doping enhances electrochemical activity and electric conductivity, contributing to pseudocapacitance. Meanwhile, the ionic liquid electrolyte enables a very wide working voltage of 3 V, leading to a high energy density up to 163.8 W h kg(-1). The fabricated supercapacitor can light up a LED for a long while with low self-discharge, showing good potential for practical application.