▎ 摘　　要

Yolk-shell NiO microspheres are modified by two types of functionalized graphene quantum dots (denoted as NiO/GQDs) via a facile solvothermal treatment. The modification of GQDs on the surface of NiO greatly boosts the stability of the NiO/GQD electrode during long-term cycling. Specifically, the NiO with carboxyl-functionalized GQDs (NiO/GQDsCOOH) exhibits better performances than NiO with amino-functionalized GQDs (NiO/GQDsNH(2)). It delivers a capacity of approximate to 1081 mAh g(-1) (NiO contribution: approximate to 1182 mAh g(-1)) after 250 cycles at 0.1 A g(-1). In comparison, NiO/GQDsNH(2) electrode holds approximate to 834 mAh g(-1) of capacity, while the bald NiO exhibits an obvious decline in capacity with approximate to 396 mAh g(-1) retained after cycling. Except for the yolk-shell and mesoporous merits, the superior performances of the NiO/GQD electrode are mainly ascribed to the assistance of GQDs. The GQD modification can support as a buffer alleviating the volume change, improve the electronic conductivity, and act as a reservoir for electrolytes to facilitate the transportation of Li+. Moreover, the enrichment of carboxyl/amino groups on GQDs can further donate more active sites for the diffusion of Li+ and facilitate the electrochemical redox kinetics of the electrode, thus together leading to the superior lithium storage performance.