• 文献标题:   Novel method of preparing CoFe2O4/graphene by using steel rolling sludge for supercapacitor
  • 文献类型:   Article
  • 作  者:   LIU P, CHEN HY, CHANG X, XUE Y, ZHOU JW, ZHAO ZC, LIN HL, HAN S
  • 作者关键词:   steel rolling sludge, cofe2o4/graphene, porous nanostructure, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shanghai Inst Technol
  • 被引频次:   16
  • DOI:   10.1016/j.electacta.2017.02.088
  • 出版年:   2017

▎ 摘  要

Steel rolling sludge containing high amounts of iron was recycled for the first time via a facile hydrothermal method and used as ferric ions source for CoFe2O4/graphene nanocomposite electrode. CoFe2O4 agglomeration is weakened by introducting graphene, which is crucial for improving efficient ions transport pathways in energy storage devices. The CoFe2O4/graphene complex exhibits a rough morphology and a porous nanostructure with a high specific surface area of 191.5 m(2) g (1). The material also shows excellent Faradaic redox reactions with high specific capacity of 166.5C g (1) and 127.0C g (1) at 0.5 and 10 A g (1), respectively, which are higher than that of simple, dense CoFe2O4 particles (121.6C g (1) at 0.5 A g (1)). Furthermore, the electrode demonstrates outstanding cycle stability with 79.3% capacitance retained after 5000 cycles. Hence, the proposed resource reuse strategy can be used to prepare CoFe2O4/graphene nanocomposites for supercapacitors. (C) 2017 Elsevier Ltd. All rights reserved.