• 文献标题:   Hydrogen adsorption on graphene foam synthesized by combustion of sodium ethoxide
  • 文献类型:   Article
  • 作  者:   LYTH SM, SHAO HY, LIU JF, SASAKI K, AKIBA E
  • 作者关键词:   graphene, hydrogen, sorption, storage, synthesi
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Kyushu Univ
  • 被引频次:   25
  • DOI:   10.1016/j.ijhydene.2013.10.044
  • 出版年:   2014

▎ 摘  要

Hydrogen storage is a crucial technology for the realization of a carbon-neutral society. However, few materials have been able to approach useful hydrogen storage capacity at reasonable temperatures and pressures. Graphene has an extremely high surface-area-to-weight ratio, is strong, cheap, chemically inert, and environmentally benign. As such it may be an ideal substrate for hydrogen storage. Here we present synthesis of graphene foam by combustion of sodium ethoxide. This technique is low-cost, scalable, and results in a three-dimensional graphene network with a surface area of more than 1200 m(2)/g. It is applied as a hydrogen storage material at liquid nitrogen temperature, with a capacity of 2.1 wt%. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.