▎ 摘 要
Sodium-ion batteries (SIBs) have emerged as a promising alternative to Lithium-ion batteries (LIBs) for energy storage applications, due to abundant sodium resources, low cost, and similar electrochemical performance. However, the large radius of Na+ and high molar mass compared to Li+, result in large volume strain during charge/discharge and low reversible capacity and poor cycling stability. Due to exceptional physical and chemical properties, graphene has attracted increasing attention as a potential anode material for SIBs. When integrated with other nanomaterials in electrodes, graphene can improve the electrical conductivity, accommodate the large volume change and enhance reaction kinetics. This paper provides a systematic review of recent progress in the application of graphene based anodes for SIBs, with a focus on preparation, structural configuration, Na+ storage mechanism and electrochemical performance. Additionally, some challenges and future perspectives are provided to improve the sodium storage performance of graphene based electrodes. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.