• 文献标题:   Zirconium oxide with graphene oxide anchoring for improved heavy metal ions adsorption: Isotherm and kinetic study
  • 文献类型:   Article
  • 作  者:   ALMHYAWI SR, BADER DMD, BAJABER MA, ABD EL DAYEM SM, RAGAB AH, ABD ELRAHEM KA, GADO MA, ATIA BM, CHEIRA MF
  • 作者关键词:   uranium sorption, zirconium oxide, graphene oxide, kinetic, thermodynamic circumstance
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH TECHNOLOGYJMR T
  • ISSN:   2238-7854 EI 2214-0697
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.jmrt.2022.11.121 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

Heavy metal contamination is a major environmental issue worldwide and a significant public health risk. However, developing environmentally sustainable and technically viable solutions or adsorbents for treating water contamination caused by heavy metals is ur-gently needed. In this work, an eco-friendly approach of obtaining a new composite ma-terial called ZrO2/GO that was prepared from the synthesized nano zirconium oxide (ZrO2) and graphene oxide (GO) prepared from spent carbon rods in zinc carbon batteries. ZrO2/ GO was analyzed by XRD, SEM, BET, EDX, and FTIR to learn more about its composition and structure. The batch approach determined the optimal sorption conditions, including pH4, 50 mg ZrO2/GO, 150 mg/L U(VI), and 50 min of sorption time. ZrO2/GO was found to have a 128 mg/g sorption capacity. The Langmuir and 2nd-order kinetic equations can be exploited to elucidate the adsorption approach with reasonable accuracy. Since sorption is exothermic when it occurs naturally, thermodynamic restrictions were also envisioned. ZrO2/GO retains over 92% heavy metal ions (VI) removal efficiency even after 7 cycles. ZrO2/GO shows assurance as a potent sorbent material to extract hexavalent heavy metal ions and adsorption capacity from massive solution volumes.(c) 2022 Published by Elsevier B.V. This is an open access article under the CC BY-NC-NDlicense (http://creativecommons.org/licenses/by-nc-nd/4.0/).