• 文献标题:   Perovskite Solar Cells with Large-Area CVD-Graphene for Tandem Solar Cells
  • 文献类型:   Article
  • 作  者:   LANG F, GLUBA MA, ALBRECHT S, RAPPICH J, KORTE L, RECH B, NICKEL NH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • ISSN:   1948-7185
  • 通讯作者地址:   Helmholtz Zentrum Berlin Mat Energie GmbH
  • 被引频次:   97
  • DOI:   10.1021/acs.jpclett.5b01177
  • 出版年:   2015

▎ 摘  要

Perovskite solar cells with transparent contacts may be used to compensate for thermalization losses of silicon solar cells in tandem devices. This offers a way to outreach stagnating efficiencies. However, perovskite top cells in tandem structures require contact layers with high electrical conductivity and optimal transparency. We address this challenge by implementing large-area graphene grown by chemical vapor deposition as a highly transparent electrode in perovskite solar cells, leading to identical charge collection efficiencies. Electrical performance of solar cells with a graphene-based contact reached those of solar cells with standard gold contacts. The optical transmission by far exceeds that of reference devices and amounts to 64.3% below the perovskite band gap. Finally, we demonstrate a four-terminal tandem device combining a high band gap graphene-contacted perovskite top solar cell (E-g = 1.6 eV) with an amorphous/crystalline silicon bottom solar cell (E-g = 1.12 eV).