• 文献标题:   A facile one-pot synthesis of carbon nitride dots-reduced graphene oxide nanocomposites for simultaneous enhanced detecting of dopamine and uric acid
  • 文献类型:   Article
  • 作  者:   YANG ZY, ZHENG XH, LI Z, ZHENG JB
  • 作者关键词:  
  • 出版物名称:   ANALYST
  • ISSN:   0003-2654 EI 1364-5528
  • 通讯作者地址:   Northwest Univ
  • 被引频次:   10
  • DOI:   10.1039/c6an00640j
  • 出版年:   2016

▎ 摘  要

In this study, we described the facile synthesis of carbon nitride dots-reduced graphene oxide nanocomposites (CNDs-rGO) and their application for the enhanced electrochemical determination of dopamine (DA) and uric acid (UA). CNDs-rGO were synthesized for the first time through a green and facile one-step approach, carried out by hydrothermal heat-treatment of an aqueous solution containing GO and chitosan without introduction of other reducing agents or surface modifier. Then, the morphology and composition of CNDs-rGO nanocomposites were characterized by transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. TEM observations revealed that CNDs with a size of about 5.0 nm were homogeneously and densely distributed on the surface of rGO. Electrochemical investigations indicated that CNDs-rGO nanocomposites exhibited an excellent performance toward DA and UA. The linear range for DA was estimated to be from 80 nM to 227 mu M with a sensitivity of 154.3 mu A mM(-1) cm(-2) and a low detection limit of 0.03 mu M. Meanwhile, the linear range for UA was estimated to be from 80 nM to 328 mu M with a high sensitivity of 178.1 mu A mM(-1) cm(-2) and a low detection limit of 0.05 mu M. Therefore, CNDs-rGO nanocomposites showed great application potential for constructing electrochemical sensors for the detection of DA and UA.