• 文献标题:   Electrocatalytic performance of CuO/graphene nanocomposites for Li-O-2 batteries
  • 文献类型:   Article
  • 作  者:   KIM DS, LEE GH, LEE S, KIM JC, LEE HJ, KIM BK, KIM DW
  • 作者关键词:   cuo, graphene, electrocatalyst, oxygen electrode, lio2 batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Korea Univ
  • 被引频次:   5
  • DOI:   10.1016/j.jallcom.2016.11.317
  • 出版年:   2017

▎ 摘  要

A hybrid catalyst system of a porous CuO nanowire/leaf mixture anchored onto graphene (p-CuO/G hybrid) was prepared as an oxygen-electrode electrocatalyst for lithiumeoxygen (LieO(2)) batteries. The p-CuO/G hybrid was prepared via the hybridization of a porous 1D/2D CuO mixture with 2D graphene. As an oxygen-electrode electrocatalyst for LieO(2) cells, the p-CuO/G hybrid exhibited high reversibility with a low voltage gap compared with a graphene electrode during 120 dischargeecharge cycles under a fixed capacity regime of 1000 mA h g(-1). We demonstrated the oxygen reduction and evolution kinetics of the p-CuO/G hybrid using electrochemical impedance spectroscopy. (C) 2016 Elsevier B.V. All rights reserved.