• 文献标题:   Polyethersulfone membranes: From ultrafiltration to nanofiltration via the incorporation of APTS functionalized-graphene oxide
  • 文献类型:   Article
  • 作  者:   LUQUEALLED JM, ABDELKARIM A, ALBERTO M, LEAPER S, PEREZPAGE M, HUANG K, VIJAYARAGHAVAN A, ELKALLINY AS, HOLMES SM, GORGOJ P
  • 作者关键词:   nanofiltration nf, mixed matrix membranes mmms, functionalized graphene oxide, polyethersulfone pes, antifouling
  • 出版物名称:   SEPARATION PURIFICATION TECHNOLOGY
  • ISSN:   1383-5866 EI 1873-3794
  • 通讯作者地址:   Univ Manchester
  • 被引频次:   5
  • DOI:   10.1016/j.seppur.2019.115836
  • 出版年:   2020

▎ 摘  要

In this study, graphene oxide (GO) functionalized with 3-aminopropyltriethoxysilane (APTS) was incorporated into polyethersulfone (PES) membranes prepared by non-solvent induced phase inversion (NIPS). This resulted in increased rejections of protein bovine serum albumin (BSA), divalent salts (MgSO4) and low-molecular weight dyes (sunset yellow and acridine orange). The structural properties of the prepared mixed matrix membranes (MMMs) as well as pure PES control membranes were investigated through scanning electron microscopy (SEM), atomic force microscopy (AFM), specific surface area, zeta potential and contact angle. It was found that the introduction of APTS-GO fillers in the polymer matrix made the membranes' application range move from ultrafiltration (UF) for pure PES membranes to nanofiltration (NF) for MMMs with a molecular weight cut off (MWCO) of similar to 1000 Da. Furthermore, membranes prepared by using only 0.1 wt% APTS-GO in combination with 1 wt% of pore-forming agent polyvinylpyrrolidone (PVP 40 K) in the casting solution exhibited high water permeance values of 9.9 LMHbar (L m(-2) h(-1) bar(-1)) at low operating pressures of 4 bar and rejections of dyes and BSA > 95%. In addition, improved anti-fouling properties and tensile strength values were obtained when incorporating the functionalized GO.