• 文献标题:   Resolving localized phonon modes on graphene/Ir(111) by inelastic atom scattering
  • 文献类型:   Article
  • 作  者:   AL TALEB A, ANEMONE G, FARIAS D, MIRANDA R
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Univ Autonoma Madrid
  • 被引频次:   2
  • DOI:   10.1016/j.carbon.2018.03.008
  • 出版年:   2018

▎ 摘  要

Low energy (few meV) acoustic phonon modes of graphene/Ir (111) have been measured using inelastic helium atom scattering (HAS). The data clearly show two vibrational modes with energies 4.6 and 7.2 meV at (Gamma) over bar with dispersionless branches due to Umklapp scattering. The phonons observed are not the ones expected for a free-standing graphene monolayer, in spite of the weak interaction between graphene and Ir (111). The measured parabolic dispersion of the flexural mode along the (Gamma M) over bar direction allows determining the bending rigidity kappa = (0.80 +/- 0.07) eV. Inelastic HAS measured at diffraction conditions proves that the moire superstructure results in localized phonon modes related to the upper and the lower regions of the graphene superstructure. Our study shows that inelastic HAS is suitable to resolve low-energy vibrations spatially localized on structures in the nanometer range. (C) 2018 Elsevier Ltd. All rights reserved.