▎ 摘　　要

Transitional metal oxides are a class of high-capacity anodes for lithium ion batteries. Drastic volume changes during cycling and intrinsically poor electronic conductivity diminish their electrochemical performances such as cycliability and high-rate capabilities. This study reports an unprecedented MoO2/carbon network, consisting of the standing carbon-coated MoO2 nanosheets on graphene nanosheets to solve these problems. The obtained MoO2 products can be tuned to have particle-like, rod-like, or sheet-like morphologies (standing MoO2@C core-shell nanosheets or flat-lying MoO2 nanosheets) on graphene by adjusting the experimental parameters. Due to the unique three dimensional porous MoO2@C/graphene hierarchical structure, the composite manifests excellent electrochemical properties including high capacity, long cycle life and stable high-rate performances. A large reversible capacity of above 500 mA h g(-1) can be achieved after 200 cycles at a large current of 5 A g(-1).