• 文献标题:   Facile fabrication of magnetic MoO2-Salen-modified graphene-based catalyst for epoxidation of alkenes
  • 文献类型:   Article
  • 作  者:   LI ZF, YANG CL, MA YY, LI P, GUAN JQ, KAN QB
  • 作者关键词:   coreshell catalyst, graphene, magnetism, cyclooctene
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   4
  • DOI:   10.1002/aoc.3742
  • 出版年:   2017

▎ 摘  要

A facile, green and efficient method for the immobilization of MoO2-Salen onto graphene hybridized with glucose-coated magnetic Fe3O4 nanoparticles is proposed to fabricate a magnetic organic-inorganic hybrid heterogeneous RGO/Fe3O4@C-Salen-MoO2 catalyst for the epoxidation of cyclooctene and geraniol using tert-butyl hydroperoxide or H2O2 as oxidant. Carbon-coated Fe3O4 can improve the stability and add functional -OH groups on the surface of Fe3O4. The fabricated composite exhibited good performance due to good dispersion of MoO2-Salen active sites. The catalyst can be easily separated from the reaction system using a permanent magnet and used three times without significantly losing its catalytic activity and selectivity.