▎ 摘 要
A facile, green and efficient method for the immobilization of MoO2-Salen onto graphene hybridized with glucose-coated magnetic Fe3O4 nanoparticles is proposed to fabricate a magnetic organic-inorganic hybrid heterogeneous RGO/Fe3O4@C-Salen-MoO2 catalyst for the epoxidation of cyclooctene and geraniol using tert-butyl hydroperoxide or H2O2 as oxidant. Carbon-coated Fe3O4 can improve the stability and add functional -OH groups on the surface of Fe3O4. The fabricated composite exhibited good performance due to good dispersion of MoO2-Salen active sites. The catalyst can be easily separated from the reaction system using a permanent magnet and used three times without significantly losing its catalytic activity and selectivity.